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No, you can't use Glycerine please
If baby teeth aren't brushed properly, bacteria (plaque) might form on the teeth — which can lead to tooth discolouration. Some Infant medications containing iron, such as supplemental vitamins, blood tonic might cause stains on baby teeth. For toothpaste, I will recommend . " milk teeth toothpaste". You can find them in the supermarket or order online
Paediatrician